Goliad, the District 30-2A champion, will take a 28-8 record into the match. Natalia is the third-place team from District 29-2A.
The Tigerettes finished district play undefeated Tuesday with a 25-22, 25-21, 25-14 win over Industrial.
Megan Hilscher and Ashtin Zamzow each had 11 kills. Bethany Salziger had 15 digs and Hilscher and Sydney Morris each added 13.
Zamzow and Mallory Bruns each had three blocks and Kendall Coles tallied 21 assists.